POSS as building-blocks for the preparation of polysilsesquioxanes through an innovative synthetic approach.

نویسندگان

  • Stefano Marchesi
  • Fabio Carniato
  • Luca Palin
  • Enrico Boccaleri
چکیده

A novel solvent-free solid-state synthesis was used to prepare a non-crystalline polysilsesquioxane sample, with a peculiar viscous form. The material was synthesized through direct self-condensation of a partially condensed polyhedral oligomeric silsesquioxane (POSS) and its physico-chemical properties, in terms of composition/structure, thermal stability and hydrophobicity, were investigated.

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عنوان ژورنال:
  • Dalton transactions

دوره 44 5  شماره 

صفحات  -

تاریخ انتشار 2015